Daudén Ibáñez| 13 |  | De Sanctis | |||
| 4 |  | Dani Alves | |||
| 15 |  | Mosquera | |||
| 26 |  | Crespo | |||
| 3 |  | Dragutinović | 7 | ||
| 17 |  | Capel | 44 44 | ||
| 8 |  | Poulsen | |||
| 6 |  | Adriano | 53 | ||
| 25 |  | Maresca | 53 | ||
| 19 |  | Chevantón | 68 | ||
| 10 |  | Luís Fabiano |
| 1 |  | Víctor Valdés | |||
| 5 |  | Puyol | 89 | ||
| 4 |  | Márquez | 13 | ||
| 3 |  | Milito | 59 | ||
| 22 |  | Abidal | 77 | ||
| 15 |  | Edmílson | 75 | ||
| 8 |  | Iniesta | |||
| 6 |  | Xavi | |||
| 17 |  | Giovani dos Santos | 89 | 30 | |
| 14 |  | Henry | 24 | ||
| 9 |  | Eto'o | 85 |
Substitutes
| 11 |  | Renato | 53 | ||
| 7 |  | Jesús Navas | 53 | 89 | |
| 9 |  | Kerzhakov | 68 | ||
| 28 |  | Fazio |
| 7 |  | Guðjohnsen | 85 | ||
| 21 |  | Thuram | 75 | ||
| 27 |  | Bojan | 89 | ||
| 11 |  | Zambrotta | |||
| 28 |  | Oier Olazábal |
Managers
Milestones
Goal #1 of Capel in King's Cup
Match #1 of Crespo in King's Cup
Match #1 of Milito in King's Cup with club Barcelona