Medina Cantalejo| 1 |  | César | |||
| 14 |  | Ponzio | 53 | ||
| 6 |  | Milito | 64 | ||
| 5 |  | Álvaro | 6 | ||
| 12 |  | Toledo | 81 | ||
| 21 |  | Zapater | |||
| 18 |  | Óscar González | |||
| 16 |  | Celades | 75 | ||
| 8 |  | Cani | 75 | 66 | |
| 17 |  | Ewerthon | 24 27 | ||
| 22 |  | Diego Milito | 22 93 |
| 25 |  | Jorquera | |||
| 23 |  | Oleguer | |||
| 2 |  | Belletti | 58 | 47 | |
| 4 |  | Márquez | 32 | ||
| 12 |  | Van Bronckhorst | |||
| 24 |  | Iniesta | |||
| 17 |  | Van Bommel | 58 | ||
| 15 |  | Edmílson | 49 | ||
| 19 |  | Messi | |||
| 10 |  | Ronaldinho | 61 | ||
| 7 |  | Larsson | 75 | 37 |
Substitutes
| 9 |  | Sergio García | 75 | ||
| 4 |  | Cuartero | 81 | ||
| 20 |  | Generelo | 75 | ||
| 25 |  | Valbuena | |||
| 7 |  | Movilla |
| 18 |  | Gabri | 58 | ||
| 11 |  | Maxi López | 75 | ||
| 14 |  | Ezquerro | 58 | ||
| 1 |  | Víctor Valdés | |||
| 16 |  | Sylvinho |
Managers
Milestones
Goal #1 of Diego Milito in King's Cup
Doublet #1 of Diego Milito in King's Cup
Match #1 of Edmílson in King's Cup