Pérez Lasa| 13 |  | Diego López | |||
| 18 |  | Ángel | |||
| 12 |  | Cygan | |||
| 4 |  | Godín | |||
| 5 |  | Capdevila | 59 | ||
| 21 |  | Bruno Soriano | |||
| 8 |  | Cazorla | |||
| 7 |  | Pirès | 66 | ||
| 6 |  | Josico | 56 | ||
| 22 |  | Rossi | 74 | ||
| 15 |  | Nihat | 31 |
| 1 |  | Víctor Valdés | |||
| 11 |  | Zambrotta | |||
| 21 |  | Thuram | |||
| 4 |  | Márquez | 27 | ||
| 3 |  | Milito | |||
| 16 |  | Sylvinho | |||
| 20 |  | Deco | 73 | ||
| 8 |  | Iniesta | |||
| 6 |  | Xavi | 81 | ||
| 17 |  | Giovani dos Santos | 45 | ||
| 14 |  | Henry | 67 |
Substitutes
| 19 |  | Senna | 56 | 69 | |
| 14 |  | Matías Fernández | 66 | ||
| 11 |  | Tomasson | 74 | ||
| 1 |  | Viera | |||
| 3 |  | Josemi |
| 7 |  | Guðjohnsen | 81 | ||
| 27 |  | Bojan | 67 | ||
| 19 |  | Messi | 45 | 87 | |
| 13 |  | Pinto | |||
| 23 |  | Oleguer |
Managers
Milestones
Match #1 of Capdevila in King's Cup with club Villarreal