1
González Vázquez| 25 |  | Dudek | |||
| 4 |  | Sergio Ramos | |||
| 2 |  | Míchel Salgado | |||
| 16 |  | Heinze | |||
| 12 |  | Marcelo | 62 | ||
| 24 |  | Balboa | |||
| 14 |  | Guti | 92 | ||
| 11 |  | Robben | 31 | ||
| 8 |  | Gago | |||
| 20 |  | Higuaín | |||
| 9 |  | Soldado | 62 |
| 25 |  | Ricardo Molina | |||
| 2 |  | David Malo | |||
| 19 |  | Germán | |||
| 15 |  | Alán Baró | |||
| 3 |  | Catalá | |||
| 20 |  | Azkoitia | 54 | ||
| 8 |  | Álvaro | |||
| 6 |  | Tito | 79 | ||
| 22 |  | Borja | 67 | 65 | |
| 18 |  | Joan Tomàs | 57 | ||
| 14 |  | Cañadas |
Substitutes
| 18 |  | Saviola | 62 | ||
| 22 |  | Miguel Torres | 62 | ||
| 13 |  | Codina | |||
| 15 |  | Drenthe | |||
| 19 |  | Júlio Baptista |
| 16 |  | Cavas | 79 | ||
| 10 |  | Capi | 57 | ||
| 9 |  | Luis Gil | 67 | ||
| 1 |  | Unanua | |||
| 17 |  | Héctor Bosque |
Managers
Milestones
Goal Against #50 of Alicante in King's Cup (Min 31)
Goal #1 of Robben in King's Cup
Match #1 of Marcelo in King's Cup