Megía Dávila| 13 |  | Pinto | |||
| 20 |  | Dani Alves | |||
| 5 |  | Puyol | 60 | ||
| 3 |  | Piqué | 56 | ||
| 16 |  | Sylvinho | |||
| 28 |  | Busquets | 32 | ||
| 21 |  | Hleb | 70 | ||
| 6 |  | Xavi | |||
| 10 |  | Messi | |||
| 7 |  | Guðjohnsen | |||
| 11 |  | Bojan | 73 | 34 48 |
| 25 |  | Cristian Álvarez | |||
| 15 |  | Finnan | 50 | ||
| 5 |  | Sergio Sánchez | 89 | ||
| 19 |  | Torrejón | |||
| 4 |  | Lacruz | |||
| 2 |  | Chica | 37 | ||
| 18 |  | Rufete | 65 | ||
| 14 |  | Àngel | |||
| 11 |  | Smiljanić | |||
| 24 |  | Soriano | |||
| 20 |  | Coro | 58 |
Substitutes
| 2 |  | Cáceres | 60 | ||
| 9 |  | Eto'o | 73 | ||
| 8 |  | Iniesta | 70 | ||
| 25 |  | Jorquera | |||
| 24 |  | Yaya Touré |
| 35 |  | Dídac Vilà | 89 | ||
| 21 |  | Jarque | 50 | 69 89 | |
| 8 |  | Callejón | 65 | 68 | |
| 1 |  | Kameni |
Managers
Milestones
Goal #1 of Piqué in King's Cup with club Barcelona
Doublet #1 of Bojan in King's Cup
Match #1 of Dídac Vilà in King's Cup
Match #1 of Finnan in King's Cup