Mejuto González| 13 |  | Pinto | |||
| 20 |  | Dani Alves | 83 | ||
| 4 |  | Márquez | 65 | ||
| 2 |  | Cáceres | |||
| 16 |  | Sylvinho | |||
| 28 |  | Busquets | |||
| 24 |  | Yaya Touré | 63 | ||
| 21 |  | Hleb | 72 | ||
| 8 |  | Iniesta | |||
| 7 |  | Guðjohnsen | 76 | ||
| 11 |  | Bojan | 28 |
| 1 |  | Coupet | |||
| 22 |  | Pablo Ibáñez | |||
| 21 |  | Perea | 78 | ||
| 4 |  | Pernía | |||
| 3 |  | Antonio López | |||
| 24 |  | Camacho | 46 | 35 | |
| 20 |  | Simão | |||
| 16 |  | Banega | |||
| 8 |  | Raúl García | 24 | ||
| 14 |  | Sinama-Pongolle | 23 | ||
| 10 |  | Agüero | 72 |
Substitutes
| 19 |  | De las Cuevas | 72 | ||
| 9 |  | Luis García | 46 | ||
| 25 |  | Leo Franco | |||
| 12 |  | Assunção | |||
| 17 |  | Ujfaluši |
Managers
Milestones
Goal #1 of Sinama-Pongolle in King's Cup
Goal #35900 in King's Cup (Min 23)