| Nick | Name | Age | Initial Round | Final Round | Matches | ||
|---|---|---|---|---|---|---|---|
 | Serra Ferrer | Llorenç Serra Ferrer | 47 | 1 | 31 | 31 | |
 | Rexach | Carles Rexach Cerdà | 53 | 32 | 38 | 7 |
| Nick | Name | Age | Pos | PM | SM | CM | Min | ||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 35 |  | Reina | José Manuel Reina Páez | 18 | 19 | 18 | 18 | 1669 | 1 | 0 | 0 | ||
| 2 |  | Reiziger | Michael Reizeger | 27 | 25 | 22 | 13 | 1757 | 4 | 0 | 0 | ||
| 12 |  | Sergi | Sergi Barjuán Esclusa | 29 | 33 | 30 | 24 | 2555 | 9 | 1 | 1 | ||
| 5 |  | Abelardo | Abelardo Fernández Antuña | 30 | 19 | 18 | 16 | 1596 | 5 | 1 | 1 | ||
| 3 |  | Frank De Boer | Frank De Boer | 30 | 34 | 31 | 29 | 2831 | 7 | 1 | 3 | ||
| 8 |  | Cocu | Philip John William Cocu | 30 | 35 | 32 | 25 | 2785 | 8 | 0 | 3 | ||
| 4 |  | Guardiola | Josep Guardiola Sala | 29 | 24 | 21 | 14 | 1836 | 10 | 0 | 2 | ||
| 10 |  | Rivaldo | Vitor Borba Ferreira | 28 | 35 | 34 | 29 | 2993 | 3 | 0 | 23 | ||
| 9 |  | Kluivert | Patrick Stephan Kluivert | 24 | 31 | 30 | 21 | 2574 | 5 | 0 | 18 | ||
| 21 |  | Luis Enrique | Luis Enrique Martínez García | 30 | 28 | 27 | 15 | 2183 | 9 | 2 | 9 | ||
| 11 |  | Overmars | Marc Overmars | 27 | 31 | 26 | 17 | 2324 | 2 | 0 | 8 | ||
| Substitutes | |||||||||||||
| Nick | Name | Age | Pos | PM | SM | CM | Min | ||||||
| 1 |  | Dutruel | Richard Philippe Dutruel | 28 | 15 | 15 | 13 | 1275 | 0 | 1 | 0 | ||
| 18 |  | Gabri | Gabriel Garcia De la Torre | 21 | 25 | 20 | 16 | 1755 | 7 | 0 | 2 | ||
| 20 |  | Simao | Simao Pedro Fonseca Sabrosa | 21 | 25 | 20 | 13 | 1812 | 2 | 1 | 2 | ||
| 14 |  | Gerard | Gerard López Segú | 21 | 24 | 12 | 5 | 1160 | 2 | 0 | 2 | ||
| 17 |  | Petit | Emmanuel Petit | 30 | 23 | 13 | 9 | 1386 | 5 | 0 | 1 | ||
| 25 |  | Arnau | Francesc Xavier Arnau Grabulosa | 25 | 6 | 5 | 5 | 476 | 0 | 0 | 0 | ||
| 16 |  | Xavi | Xavier Hernández Creus | 20 | 20 | 15 | 10 | 1331 | 1 | 0 | 2 | ||
| 7 |  | Alfonso | Alfonso Pérez Muñoz | 28 | 17 | 4 | 2 | 587 | 2 | 0 | 2 | ||
| 24 |  | Puyol | Carles Puyol Saforcada | 22 | 17 | 15 | 13 | 1375 | 3 | 0 | 0 | ||
| 19 |  | Dani | Daniel García Lara | 26 | 14 | 4 | 2 | 471 | 0 | 0 | 1 | ||
| 23 |  | Zenden | Boudewijn Zenden | 24 | 10 | 5 | 0 | 421 | 1 | 0 | 0 | ||
| 6 |  | De La Peña | Iván De la Peña López | 24 | 9 | 1 | 1 | 272 | 2 | 1 | 0 | ||
| 28 |  | Santamaría | Sergio Santamaría González | 20 | 1 | 0 | 0 | 21 | 0 | 0 | 0 | ||
| 15 |  | Litmanen | Jari Litmanen | 29 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | ||
| 30 |  | Bermudo | David Bermudo Rubio | 21 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | ||
 | Okunowo | Samuel Gbenga Okunowo | 21 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | |||
| 26 |  | Cuadrado | Ibán Javier Cuadrado Alonso | 21 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | ||
| 36 |  | Víctor Valdés | Víctor Valdés Arribas | 18 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | ||
Maximum scorer:
Rivaldo, 23
Most booked player:
Guardiola, 10
Most sent off player:
Luis Enrique, 2
Most used player:
Rivaldo, 2993 minutes
Wider victory at home:
7 - 0 against Athletic Club
Wider defeat at home:
1 - 2 against Villarreal
Wider victory away:
0 - 6 against Real Sociedad
Wider defeat away:
4 - 0 against Racing de Santander
Longest winning run:
4 consecutive victories
Longest losing run:
2 consecutive defeats
| Nick | Name | Age | Pos | Club from | ||
|---|---|---|---|---|---|---|
| Reina | José Manuel Reina Páez | 18 | |||
| Overmars | Marc Overmars | 27 | |||
| Dutruel | Richard Philippe Dutruel | 28 |  Celta de Vigo | ||
| Gerard | Gerard López Segú | 21 |  Valencia | ||
| Petit | Emmanuel Petit | 30 | |||
| Alfonso | Alfonso Pérez Muñoz | 28 |  Betis | ||
| De La Peña | Iván De la Peña López | 24 | |||
| Bermudo | David Bermudo Rubio | 21 | |||
| Okunowo | Samuel Gbenga Okunowo | 21 | |||
| Cuadrado | Ibán Javier Cuadrado Alonso | 21 | |||
| Víctor Valdés | Víctor Valdés Arribas | 18 | |||
| Leaving | ||||||
| Nick | Name | Age | Pos | Club to | ||
 | Hesp | Rudolfus Hurbertus Hesp | 34 | |||
 | Figo | Luis Filipe Madeira Caeiro | 27 |  Real Madrid | ||
 | Bogarde | Winston Bogarde | 29 | |||
 | Ronald De Boer | Ronald De Boer | 29 | |||
 | Dehu | Frederic Dehu | 27 | |||
 | Nano | Fernando Macedo Da Silva Rodilla | 17 |  Barcelona B | ||
 | Amunike | Emmanuel Amuneke | 29 |  Albacete | ||
 | Mario Rosas | Mario Alberto Rosas Montero | 19 |  Alavés | ||
| Competition | Type | Date | Home | Visitor | ||||
|---|---|---|---|---|---|---|---|---|
| Liga | 1 | 09/09/2000 | Barcelona | 2 | 1 | Málaga |  |  |
| Champions League | G11 | 13/09/2000 | Barcelona | 4 | 0 | Leeds | | |
| Liga | 2 | 16/09/2000 | Athletic de Bilbao | 3 | 1 | Barcelona |  | |
| Champions League | G12 | 19/09/2000 | Besiktas | 3 | 0 | Barcelona | | |
| Liga | 3 | 23/09/2000 | Barcelona | 3 | 1 | Racing de Santander | | |
| Champions League | G13 | 26/09/2000 | Barcelona | 0 | 2 | Milan | | |
| Liga | 4 | 01/10/2000 | Deportivo de la Coruña | 2 | 0 | Barcelona | | |
| Liga | 5 | 14/10/2000 | Real Sociedad | 0 | 6 | Barcelona | | |
| Champions League | G14 | 18/10/2000 | Milan | 3 | 3 | Barcelona |  | |
| Liga | 6 | 21/10/2000 | Barcelona | 2 | 0 | Real Madrid | | |
| Champions League | G15 | 24/10/2000 | Leeds | 1 | 1 | Barcelona | | |
| Liga | 7 | 28/10/2000 | Mallorca | 2 | 0 | Barcelona | | |
| Liga | 8 | 01/11/2000 | Barcelona | 1 | 1 | Numancia | | |
| Liga | 9 | 04/11/2000 | Las Palmas | 0 | 1 | Barcelona | | |
| Champions League | G16 | 08/11/2000 | Barcelona | 5 | 0 | Besiktas | | |
| Liga | 10 | 12/11/2000 | Barcelona | 1 | 2 | Villarreal | | |
| Liga | 11 | 19/11/2000 | Zaragoza | 3 | 1 | Barcelona | | |
| UEFA Cup | R321 | 23/11/2000 | Brujas | 0 | 2 | Barcelona | | |
| Liga | 12 | 26/11/2000 | Barcelona | 2 | 0 | Osasuna | | |
| Liga | 13 | 02/12/2000 | Celta de Vigo | 3 | 3 | Barcelona | | |
| UEFA Cup | R322 | 07/12/2000 | Barcelona | 1 | 1 | Brujas | | |
| Liga | 14 | 10/12/2000 | Barcelona | 4 | 2 | Espanyol | | |
| King's Cup | 3 | 12/12/2000 | Gandia | 0 | 3 | Barcelona | | |
| Liga | 15 | 16/12/2000 | Rayo Vallecano | 2 | 2 | Barcelona | | |
| Liga | 16 | 20/12/2000 | Barcelona | 3 | 2 | Alavés | | |
| King's Cup | 4 | 03/01/2001 | Ceuta | 0 | 3 | Barcelona | | |
| Liga | 17 | 07/01/2001 | Oviedo | 2 | 3 | Barcelona | | |
| King's Cup | 5 | 10/01/2001 | Torrelavega | 0 | 1 | Barcelona | | |
| Liga | 18 | 13/01/2001 | Barcelona | 3 | 1 | Valladolid | | |
| King's Cup | 6 | 16/01/2001 | Barcelona | 0 | 0 | Torrelavega | | |
| Liga | 19 | 20/01/2001 | Valencia | 0 | 1 | Barcelona | | |
| Liga | 20 | 27/01/2001 | Málaga | 0 | 0 | Barcelona | | |
| King's Cup | 7 | 30/01/2001 | Espanyol | 1 | 2 | Barcelona | | |
| Liga | 21 | 03/02/2001 | Barcelona | 7 | 0 | Athletic de Bilbao | | |
| King's Cup | 8 | 07/02/2001 | Barcelona | 1 | 1 | Espanyol | | |
| Liga | 22 | 11/02/2001 | Racing de Santander | 4 | 0 | Barcelona | | |
| UEFA Cup | VF1 | 15/02/2001 | AEK Atenas | 0 | 1 | Barcelona | | |
| Liga | 23 | 17/02/2001 | Barcelona | 2 | 3 | Deportivo de la Coruña | | |
| UEFA Cup | VF2 | 22/02/2001 | Barcelona | 5 | 0 | AEK Atenas | | |
| Liga | 24 | 25/02/2001 | Barcelona | 3 | 0 | Real Sociedad | | |
| Liga | 25 | 03/03/2001 | Real Madrid | 2 | 2 | Barcelona | | |
| UEFA Cup | QF1 | 08/03/2001 | Barcelona | 2 | 1 | Celta de Vigo | | |
| Liga | 26 | 11/03/2001 | Barcelona | 1 | 1 | Mallorca | | |
| UEFA Cup | QF2 | 15/03/2001 | Celta de Vigo | 3 | 2 | Barcelona | | |
| Liga | 27 | 18/03/2001 | Numancia | 1 | 1 | Barcelona | | |
| Liga | 28 | 01/04/2001 | Barcelona | 4 | 1 | Las Palmas | | |
| UEFA Cup | SF1 | 05/04/2001 | Barcelona | 0 | 0 | Liverpool | | |
| Liga | 29 | 08/04/2001 | Villarreal | 4 | 4 | Barcelona | | |
| Liga | 30 | 14/04/2001 | Barcelona | 4 | 4 | Zaragoza | | |
| UEFA Cup | SF2 | 19/04/2001 | Liverpool | 1 | 0 | Barcelona | | |
| Liga | 31 | 22/04/2001 | Osasuna | 3 | 1 | Barcelona | | |
| Liga | 32 | 29/04/2001 | Barcelona | 1 | 1 | Celta de Vigo | | |
| Liga | 33 | 05/05/2001 | Espanyol | 0 | 0 | Barcelona | | |
| Liga | 34 | 13/05/2001 | Barcelona | 5 | 1 | Rayo Vallecano | | |
| Liga | 35 | 19/05/2001 | Alavés | 0 | 1 | Barcelona | | |
| Liga | 36 | 27/05/2001 | Barcelona | 0 | 1 | Oviedo | | |
| Liga | 37 | 10/06/2001 | Valladolid | 2 | 2 | Barcelona | | |
| Liga | 38 | 17/06/2001 | Barcelona | 3 | 2 | Valencia | | |
| King's Cup | 9 | 21/06/2001 | Celta de Vigo | 3 | 1 | Barcelona | | |
| King's Cup | 10 | 24/06/2001 | Barcelona | 1 | 1 | Celta de Vigo | | |
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