| Nick | Name | Age | Initial Round | Final Round | Matches | ||
|---|---|---|---|---|---|---|---|
 | Quique | Enrique Sánchez Flores | 41 | 1 | 38 | 38 |
| Nick | Name | Age | Pos | PM | SM | CM | Min | ||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1 |  | Cañizares | José Santiago Cañizares Ruiz | 37 | 32 | 32 | 30 | 2786 | 3 | 1 | 0 | ||
| 2 |  | Miguel | Luis Miguel Brito García Monteiro | 26 | 30 | 27 | 27 | 2483 | 5 | 0 | 0 | ||
| 24 |  | Moretti | Emiliano Moretti | 25 | 23 | 23 | 21 | 2040 | 5 | 1 | 2 | ||
| 20 |  | Albiol | Raúl Albiol Tortajada | 21 | 36 | 35 | 33 | 3186 | 9 | 0 | 1 | ||
| 4 |  | Ayala | Roberto Fabián Ayala | 33 | 29 | 29 | 27 | 2568 | 10 | 1 | 2 | ||
| 6 |  | Albelda | David Albelda Aliqués | 29 | 25 | 25 | 15 | 2014 | 6 | 1 | 0 | ||
| 7 |  | David Villa | David Villa Sánchez | 25 | 36 | 35 | 21 | 2935 | 9 | 0 | 15 | ||
| 21 |  | Silva | David Josué Jiménez Silva | 20 | 36 | 31 | 17 | 2648 | 5 | 1 | 4 | ||
| 10 |  | Angulo | Miguel Ángel Angulo Valderrey | 29 | 36 | 27 | 13 | 2233 | 2 | 0 | 6 | ||
| 15 |  | Joaquín | Joaquín Sánchez Rodríguez | 25 | 35 | 22 | 12 | 2135 | 5 | 0 | 5 | ||
| 9 |  | Morientes | Fernando Morientes Sánchez | 30 | 24 | 17 | 9 | 1605 | 0 | 0 | 12 | ||
| Substitutes | |||||||||||||
| Nick | Name | Age | Pos | PM | SM | CM | Min | ||||||
| 25 |  | Butelle | Jean Ludovic Butelle | 23 | 8 | 6 | 6 | 634 | 2 | 0 | 0 | ||
| 16 |  | Hugo Viana | Hugo Miguel Ferreira Viana | 23 | 25 | 7 | 4 | 994 | 4 | 0 | 2 | ||
| 5 |  | Marchena | Carlos Marchena López | 27 | 22 | 19 | 16 | 1587 | 7 | 1 | 0 | ||
| 23 |  | Curro Torres | Cristóbal Emilio Torres Ruiz | 30 | 17 | 17 | 12 | 1374 | 4 | 0 | 0 | ||
| 14 |  | Vicente | Vicente Rodríguez Guillén | 25 | 16 | 13 | 6 | 1135 | 2 | 0 | 4 | ||
| 13 |  | Mora | Juan Luis Mora Palacios | 33 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | ||
| 8 |  | Baraja | Rubén Baraja Vegas | 31 | 14 | 9 | 4 | 799 | 6 | 0 | 1 | ||
| 18 |  | Jorge López | Jorge López Montaña | 28 | 14 | 2 | 0 | 294 | 3 | 1 | 0 | ||
| 17 |  | David Navarro | David Navarro Pedrós | 26 | 13 | 12 | 10 | 1005 | 6 | 0 | 1 | ||
| 19 |  | Gavilán | Jaime Gavilán Martínez | 21 | 12 | 4 | 1 | 402 | 2 | 1 | 0 | ||
| 22 |  | Edu | Eduardo César Daud Gaspar | 28 | 10 | 9 | 7 | 817 | 2 | 0 | 0 | ||
| 31 |  | Pallardó | Miguel Pallardó González | 20 | 10 | 5 | 1 | 382 | 1 | 0 | 0 | ||
| 11 |  | Regueiro | Mario Ignacio Regueiro Pintos | 28 | 6 | 1 | 1 | 227 | 2 | 1 | 0 | ||
| 3 |  | Del Horno | Asier Del Horno Cosgaya | 25 | 6 | 6 | 5 | 532 | 2 | 0 | 0 | ||
| 26 |  | Cerra | David Cerrajería Rubio | 23 | 5 | 4 | 3 | 353 | 3 | 0 | 0 | ||
| 12 |  | Tavano | Francesco Tavano | 27 | 3 | 0 | 0 | 44 | 0 | 0 | 0 | ||
| 34 |  | Javi Guerra | Javier Guerra Rodríguez | 24 | 2 | 0 | 0 | 15 | 0 | 0 | 0 | ||
| 29 |  | Córcoles | David Córcoles Alcaraz | 21 | 1 | 1 | 1 | 90 | 0 | 0 | 0 | ||
| 28 |  | Nacho Insa | Ignacio Insa Bohigues | 20 | 1 | 0 | 0 | 6 | 0 | 0 | 0 | ||
| 38 |  | Romero | Vicente Romero Romero | 19 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | ||
| 30 |  | Aarón Ñíguez | Aarón Ñíguez Esclápez | 17 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | ||
Maximum scorer:
David Villa, 15
Most booked player:
Ayala, 10
Most sent off player:
Cañizares, 1
Most used player:
Albiol, 3186 minutes
Wider victory at home:
4 - 0 against Gimnàstic de Tarragona
Wider defeat at home:
0 - 2 against Racing de Santander
Wider victory away:
0 - 1 against Atlético de Madrid
Wider defeat away:
3 - 0 against Sevilla
Longest winning run:
6 consecutive victories
Longest losing run:
3 consecutive defeats
| Nick | Name | Age | Pos | Club from | ||
|---|---|---|---|---|---|---|
| Silva | David Josué Jiménez Silva | 20 |  Celta de Vigo | ||
| Joaquín | Joaquín Sánchez Rodríguez | 25 |  Betis | ||
| Morientes | Fernando Morientes Sánchez | 30 | |||
| Gavilán | Jaime Gavilán Martínez | 21 |  Getafe | ||
| Pallardó | Miguel Pallardó González | 20 | |||
| Del Horno | Asier Del Horno Cosgaya | 25 | |||
| Cerra | David Cerrajería Rubio | 23 | |||
| Tavano | Francesco Tavano | 27 | |||
| Javi Guerra | Javier Guerra Rodríguez | 24 | |||
| Córcoles | David Córcoles Alcaraz | 21 | |||
| Nacho Insa | Ignacio Insa Bohigues | 20 | |||
| Romero | Vicente Romero Romero | 19 | |||
| Aarón Ñíguez | Aarón Ñíguez Esclápez | 17 | |||
| Leaving | ||||||
| Nick | Name | Age | Pos | Club to | ||
 | Aimar | Pablo César Aimar | 26 |  Real Zaragoza | ||
 | Mista | Miguel Ángel Ferrer Martínez | 27 |  Atlético de Madrid | ||
 | Fabio Aurelio | Fabio Aurelio Rodríguez | 26 | |||
 | Rufete | Francisco Joaquín Pérez Rufete | 29 |  Espanyol | ||
 | Kluivert | Patrick Stephan Kluivert | 29 | |||
 | Carboni | Amedeo Carboni | 40 | |||
 | Di Vaio | Marco Di Vaio | 29 | |||
 | Caneira | Marco Antonio Simoes Caneira | 26 | |||
 | Pablo Hernández | Pablo Hernández Domínguez | 20 |  Cádiz | ||
 | De Los Santos | Gonzalo De los Santos Da Rosa | 29 |  Hércules | ||
 | Pedro López | Pedro López Muñoz | 22 |  Valladolid | ||
 | Juanlu Hens | Juan Luis Hens Lorite | 21 | Hércules | ||
 | Ruz | Manuel Ruz Baños | 19 |  Gimnàstic de Tarragona | ||
| Competition | Type | Date | Home | Visitor | ||||
|---|---|---|---|---|---|---|---|---|
| Champions League | ThirdQR1 | 09/08/2006 | Salzburg | 1 | 0 | Valencia |  |  |
| Champions League | ThirdQR2 | 22/08/2006 | Valencia | 3 | 0 | Salzburg |  | |
| Liga | 1 | 26/08/2006 | Valencia | 2 | 1 | Betis | | |
| Liga | 2 | 09/09/2006 | Atlético de Madrid | 0 | 1 | Valencia | | |
| Champions League | G1 | 12/09/2006 | Olympiakos | 2 | 4 | Valencia | | |
| Liga | 3 | 17/09/2006 | Valencia | 2 | 0 | Getafe | | |
| Liga | 4 | 24/09/2006 | Barcelona | 1 | 1 | Valencia |  | |
| Champions League | G2 | 27/09/2006 | Valencia | 2 | 1 | Roma | | |
| Liga | 5 | 01/10/2006 | Valencia | 4 | 0 | Gimnàstic de Tarragona | | |
| Liga | 6 | 15/10/2006 | Celta de Vigo | 3 | 2 | Valencia | | |
| Champions League | G3 | 18/10/2006 | Valencia | 2 | 0 | Shakhtar | | |
| Liga | 7 | 22/10/2006 | Valencia | 1 | 0 | Osasuna | | |
| King's Cup | 4 | 25/10/2006 | Portuense | 1 | 2 | Valencia | | |
| Liga | 8 | 28/10/2006 | Racing de Santander | 1 | 0 | Valencia | | |
| Champions League | G4 | 31/10/2006 | Shakhtar | 2 | 2 | Valencia | | |
| Liga | 9 | 05/11/2006 | Espanyol | 1 | 1 | Valencia | | |
| King's Cup | 5 | 08/11/2006 | Valencia | 2 | 0 | Portuense | | |
| Liga | 10 | 11/11/2006 | Valencia | 1 | 1 | Athletic de Bilbao | | |
| Liga | 11 | 18/11/2006 | Sevilla | 3 | 0 | Valencia | | |
| Champions League | G5 | 22/11/2006 | Valencia | 2 | 0 | Olympiakos | | |
| Liga | 12 | 26/11/2006 | Valencia | 0 | 1 | Real Madrid | | |
| Liga | 13 | 02/12/2006 | Recreativo de Huelva | 2 | 0 | Valencia | | |
| Champions League | G6 | 05/12/2006 | Roma | 1 | 0 | Valencia | | |
| Liga | 14 | 10/12/2006 | Valencia | 4 | 0 | Deportivo de la Coruña | | |
| Liga | 15 | 16/12/2006 | Zaragoza | 0 | 1 | Valencia | | |
| Liga | 16 | 19/12/2006 | Valencia | 3 | 1 | Mallorca | | |
| Liga | 17 | 07/01/2007 | Villarreal | 0 | 1 | Valencia | | |
| King's Cup | 6 | 10/01/2007 | Getafe | 1 | 1 | Valencia | | |
| Liga | 18 | 13/01/2007 | Valencia | 3 | 0 | Levante | | |
| King's Cup | 7 | 17/01/2007 | Valencia | 2 | 4 | Getafe | | |
| Liga | 19 | 21/01/2007 | Real Sociedad | 0 | 1 | Valencia | | |
| Liga | 20 | 28/01/2007 | Betis | 2 | 1 | Valencia | | |
| Liga | 21 | 03/02/2007 | Valencia | 3 | 1 | Atlético de Madrid | | |
| Liga | 22 | 11/02/2007 | Getafe | 3 | 0 | Valencia | | |
| Liga | 23 | 18/02/2007 | Valencia | 2 | 1 | Barcelona | | |
| Champions League | VF1 | 21/02/2007 | Inter | 2 | 2 | Valencia | | |
| Liga | 24 | 25/02/2007 | Gimnàstic de Tarragona | 1 | 1 | Valencia | | |
| Liga | 25 | 03/03/2007 | Valencia | 1 | 0 | Celta de Vigo | | |
| Champions League | VF2 | 06/03/2007 | Valencia | 0 | 0 | Inter | | |
| Liga | 26 | 11/03/2007 | Osasuna | 1 | 1 | Valencia | | |
| Liga | 27 | 17/03/2007 | Valencia | 0 | 2 | Racing de Santander | | |
| Liga | 28 | 31/03/2007 | Valencia | 3 | 2 | Espanyol | | |
| Champions League | QF1 | 04/04/2007 | Chelsea | 1 | 1 | Valencia | | |
| Liga | 29 | 07/04/2007 | Athletic de Bilbao | 1 | 0 | Valencia | | |
| Champions League | QF2 | 10/04/2007 | Valencia | 1 | 2 | Chelsea | | |
| Liga | 30 | 15/04/2007 | Valencia | 2 | 0 | Sevilla | | |
| Liga | 31 | 21/04/2007 | Real Madrid | 2 | 1 | Valencia | | |
| Liga | 32 | 28/04/2007 | Valencia | 2 | 0 | Recreativo de Huelva | | |
| Liga | 33 | 05/05/2007 | Deportivo de la Coruña | 1 | 2 | Valencia | | |
| Liga | 34 | 13/05/2007 | Valencia | 2 | 0 | Zaragoza | | |
| Liga | 35 | 19/05/2007 | Mallorca | 0 | 1 | Valencia | | |
| Liga | 36 | 26/05/2007 | Valencia | 2 | 3 | Villarreal | | |
| Liga | 37 | 09/06/2007 | Levante | 4 | 2 | Valencia | | |
| Liga | 38 | 17/06/2007 | Valencia | 3 | 3 | Real Sociedad | | |
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